OPTIMIZATION OF SOX ADDITIVES OF FCC CATALYSTS BASED ON MGO-AL2O3 MIXED OXIDES PRODUCED FROM HYDROTALCITES

被引:61
作者
CORMA, A
PALOMARES, AE
REY, F
机构
[1] Instituto de Tecnología Química, UPV-CSIC, Universidad Politécnica de Valencia, 46071 Valencia, Camino de Vera s/n
关键词
FCC; HYDROTALCITES; MAGNESIA ALUMINA; MIXED OXIDES; SOX;
D O I
10.1016/0926-3373(94)00007-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of magnesium-rich Mg-Al spinels were prepared from hydrotalcites and characterized. When CeO2 was incorporated they showed a very good SO(x) absorption as FCC SO(x) additives, but their regeneration capacity was limited. Different transition metal oxides were tried as co-catalysts, and among them CuO, showed excellent properties to catalyze SO2 oxidation as well as catalyst regeneration. The SO(x) catalyst was stable when steamed at 750-degrees-C together with FCC catalysts.
引用
收藏
页码:29 / 43
页数:15
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