ORGANOMETAL COMPOUNDS OF LANTHANOIDS .96. YLIDE-LIKE OLEFIN COORDINATION IN COMPLEXES OF TRIVALENT 4F-ELEMENTS

被引：58

作者：

SCHUMANN, H

GLANZ, M

WINTERFELD, J

HEMLING, H

KUHN, N

BOHNEN, H

BLASER, D

BOESE, R

机构：

[1] UNIV TUBINGEN,INST ANORGAN CHEM,D-72076 TUBINGEN,GERMANY

[2] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,D-45117 ESSEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

LANTHANUM; NEODYMIUM; YTTRIUM; YLIDIC COMPLEXES; OLEFIN COMPLEXES;

D O I：

10.1016/0022-328X(95)05435-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(Me(3)Si)(2)N](3)Ln (Ln = La (1) or Nd (2)) and (C8H8)Y(C(5)Me(5)) (3) react with 1,3,4,5-tetramethyl-2-methylenimidazolin (4) to yield the ylidic olefin complexes [(Me(3)Si)(2)N](3)Ln[CH2 = CN(Me)C(Me) = C(Me)N(Me)] (Ln = La (5) or Nd (6)) and (C8H8)Y(C(5)Me(5))[CH2 = CN(Me)C(Me) = C(Me)N(Me)] (7). The molecular structures of 6 and 7 have been determined by X-ray diffraction.

引用

页码：C14 / C18

页数：5

共 43 条

[1] STRUCTURE OF TRIS(BIS(TRIMETHYLSILYL)AMIDO)NEODYMIUM(III), ND[N(SI(CH3)3)2]3
ANDERSEN, RA
TEMPLETON, DH
ZALKIN, A
[J]. INORGANIC CHEMISTRY, 1978, 17 (08) : 2317 - 2319
[2] LOW COORDINATION NUMBERS IN LANTHANIDE AND ACTINIDE COMPOUNDS .1. PREPARATION AND CHARACTERIZATION OF TRIS[BIS(TRIMETHYLSILYL)-AMIDO]LANTHANIDES
BRADLEY, DC
GHOTRA, JS
HART, FA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (10): : 1021 - 1027
[3] 3-COORDINATION IN LANTHANIDE CHEMISTRY - TRIS[BIS(TRIMETHYLSILYL)AMIDO]LANTHANIDE(III) COMPOUNDS
BRADLEY, DC
GHOTRA, JS
HART, FA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (06) : 349 - &
[4] PREPARATION OF THE 1ST ETA-2-OLEFIN COMPLEX OF A 4F-TRANSITION METAL, (ME5C5)2YB(MU-C2H4)PT(PPH3)2
BURNS, CJ
ANDERSEN, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) : 915 - 917
[5] REACTIVITY OF DISTORTED C5H5FE(CO)2(OLEFIN) CATIONS TOWARD NUCLEOPHILIC-ATTACK
CHANG, TCT
FOXMAN, BM
ROSENBLUM, M
STOCKMAN, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (24) : 7361 - 7362
[6] X-RAY CRYSTALLOGRAPHIC DETERMINATION OF STRUCTURE OF (PI-C5H5)FE(CO)2(C8H8)+! SBF6-!, A HEPTAFULVENE DERIVATIVE OF IRON(II)
CHURCHIL.MR
FENNESSE.JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (17): : 1056 - &
[7] FORMATION AND MOLECULAR-STRUCTURE OF PERMETHYLYTTROCENE METHYL TETRAHYDROFURANATE
DENHAAN, KH
DEBOER, JL
TEUBEN, JH
SMEETS, WJJ
SPEK, AL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 327 (01) : 31 - 38
[8] SYNTHESIS OF MONOMERIC PERMETHYLYTTROCENE DERIVATIVES - THE CRYSTAL-STRUCTURES OF ETA-5-C5H5YN(SIME3)2 AND ETA-5-C5H5YCH(SIME3)2
DENHAAN, KH
DEBOER, JL
TEUBEN, JH
SPEK, AL
KOJICPRODIC, B
HAYS, GR
HUIS, R
[J]. ORGANOMETALLICS, 1986, 5 (08) : 1726 - 1733
[9] DERIENZI A, 1976, GAZZ CHIM ITAL, V106, P765
[10] LANTHANIDE ALKOXIDES .3. 4-COORDINATE ANIONIC NEODYMIUM(III) ALKOXIDES AND AMIDES
EDELMANN, FT
STEINER, A
STALKE, D
GILJE, JW
JAGNER, S
HAKANSSON, M
[J]. POLYHEDRON, 1994, 13 (04) : 539 - 546

← 1 2 3 4 5 →