GENERATION OF 1,2-DIOXETANE DECOMPOSITION PRODUCTS IN THE OXIDATION OF 3-PHENYL-2-METHYLBENZOFURAN EPOXIDE BY DIMETHYLDIOXIRANE AND THE OXODIPEROXOMOLYBDENUM COMPLEX

被引：8

作者：

ADAM, W

SAUTER, M

机构：

[1] Institute of Organic Chemistry, University of Würzburg, D-97074 Würzburg, Am Hubland

来源：

TETRAHEDRON | 1994年 / 50卷 / 28期

关键词：

BENZOFURAN; EPOXIDE; DIOXETANE; 1,2,4-TRIOXANE; OXIDATION; DIMETHYLDIOXIRANE; OXODIPEROXOMOLYBDENUM;

D O I：

10.1016/S0040-4020(01)85562-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxygen transfer reaction of dimethyldioxirane (DMD) and the oxodiperoxomolybdenum complex [HMPA-MoO(O-2)(2)] on 3-phenyl-2-methylbenzofuran epoxide (2) affords the 1,2-dioxetane decomposition products, namely the keto ester 5 and the 1,3-benzodioxole 7, the latter through rearrangment of the intermediary spiroepoxide 6; neither the dioxetane 4 nor the 1,2,4-trioxane 8 serve as precursors.

引用

页码：8393 / 8398

页数：6

共 22 条

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