SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF BIS(FULVALENE)DIIRON ELECTRODE FILMS

被引：21

作者：

SAKAMOTO, K ^{[1
]}

NISHIHARA, H ^{[1
]}

ARAMAKI, K ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 12期

关键词：

D O I：

10.1039/dt9920001877

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical reduction of newly synthesised bis(fulvalene)diiron derivatives, [Fe2(C10H8) (C10H8-nRn)] (R = CCl=CHCHO, n = 1 or 3), in NBu4ClO4-MeCN leads to the deposition of stable electroactive films on glassy carbon and, indium-tin oxide coated glass electrodes. The difference in the number of substituents affects the electropolymerization reaction rate and physical and electrochemical properties of the polymer films. The electrode films control the reversibility in redox reactions of organic and organometallic electron acceptors such as p-benzoquinones and a cobaltocenium salt in acetonitrile.

引用

页码：1877 / 1881

页数：5

共 45 条

[1] CHARGE-TRANSFER COMPLEX-FORMATION PROMOTED BY AN ELECTRIC-FIELD AT THE INTERFACE OF A FERROCENE COBALTOCENIUM BILAYER FILM [J].

ANDO, Y ;

NISHIHARA, H ;

ARAMAKI, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) :1430-1432

[2] ELECTROCATALYTIC SYNTHESIS OF A COBALTOCENIUM FERROCENE BILAYER-LIKE FILM ACTING AS A SOLID-STATE DIODE [J].

ANDO, Y ;

NISHIHARA, H ;

ARAMAKI, K .

CHEMISTRY LETTERS, 1990, (08) :1399-1402

[3] THEORY OF LINEAR SWEEP VOLTAMMETRY WITH FINITE DIFFUSION SPACE [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 146 (02) :417-424

[4] THEORY OF LINEAR SWEEP VOLTAMMETRY WITH FINITE DIFFUSION SPACE .2. TOTALLY IRREVERSIBLE AND QUASI-REVERSIBLE CASES [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 160 (1-2) :33-45

[5] ELECTROACTIVE POLYMERS AND MACROMOLECULAR ELECTRONICS [J].

CHIDSEY, CED ;

MURRAY, RW .

SCIENCE, 1986, 231 (4733) :25-31

[6] CRYSTAL AND MOLECULAR STRUCTURE OF BIS(FULVALENE)DIIRON [J].

CHURCHILL, MR ;

WORMALD, J .

INORGANIC CHEMISTRY, 1969, 8 (09) :1970-+

[7] ORGANIC SOLID-STATE .10. "1,1'-BIFERROCENYLENE[FE(II)FE(III)] SALTS [J].

COWAN, DO ;

LEVANDA, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (26) :9271-9272

[8] ORGANIC SOLID STATE . ELECTRON TRANSFER IN A MIXED VALENCE SALT OF BIFERROCENE [J].

COWAN, DO ;

KAUFMAN, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (01) :219-&

[9] MOSSBAUER AND MAGNETIC SUSCEPTIBILITY STUDIES OF BIFERROCENYLENE(II,III) PICRATE [J].

COWAN, DO ;

LEVANDA, C ;

COLLINS, RL ;

CANDELA, GA ;

MUELLERW.UT ;

EILBRACHT, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (10) :329-330

[10] CHEMICAL MICROSTRUCTURES ON ELECTRODES [J].

FAULKNER, LR .

CHEMICAL & ENGINEERING NEWS, 1984, 62 (09) :28-&

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