SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF BIS(FULVALENE)DIIRON ELECTRODE FILMS

被引：21

作者：

SAKAMOTO, K ^{[1
]}

NISHIHARA, H ^{[1
]}

ARAMAKI, K ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 12期

关键词：

D O I：

10.1039/dt9920001877

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical reduction of newly synthesised bis(fulvalene)diiron derivatives, [Fe2(C10H8) (C10H8-nRn)] (R = CCl=CHCHO, n = 1 or 3), in NBu4ClO4-MeCN leads to the deposition of stable electroactive films on glassy carbon and, indium-tin oxide coated glass electrodes. The difference in the number of substituents affects the electropolymerization reaction rate and physical and electrochemical properties of the polymer films. The electrode films control the reversibility in redox reactions of organic and organometallic electron acceptors such as p-benzoquinones and a cobaltocenium salt in acetonitrile.

引用

页码：1877 / 1881

页数：5

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