RING EXPANSION OF AN ALPHA-BROMOALKYNOL CAMPHOR BY MEANS OF IODINE AND KOSER REAGENT

被引:27
作者
BOVONSOMBAT, P [1 ]
MCNELIS, E [1 ]
机构
[1] NYU,DEPT CHEM,NEW YORK,NY 10003
关键词
D O I
10.1016/S0040-4039(00)79328-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The bromoethynyl adduct of camphor was treated with equimolar amounts of iodine and Koser's reagent (HTIB) to afford in good yield and in good stereospecificity a (Z)-bromoiodoenone, a synthon for enantiospecific syntheses.
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页码:4277 / 4280
页数:4
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