BINUCLEAR ALKYL COMPLEXES - UNUSUAL ETHYLENE ADDUCTS AND FACILE C-H ACTIVATION OF A METHYL-GROUP BY AN ADJACENT METAL

被引：31

作者：

ANTWINSIAH, F ^{[1
]}

COWIE, M ^{[1
]}

机构：

[1] UNIV ALBERTA,DEPT CHEM,EDMONTON T6G 2G2,ALBERTA,CANADA

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1021/om00046a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [MIr(CO)3(dppm)2] (M = Rh, Ir; dppm = Ph2PCH2PPh2) with methyl triflate yield [RhIr(CH3)(CO)3(dppm)2] [CF3SO3] and the unusual product of C-H activation of a methyl group [Ir2H(CO)3(mu-CH2)(dppm)2] [CF3SO3], respectively. The reactivities of these species with small molecules such as H-2, CO, C2H4, and PR3 are reported.

引用

页码：3157 / 3160

页数：4

共 34 条

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