HOMOPOLYATOMIC AND HETEROPOLYATOMIC HALOGEN CATIONS

被引：16

作者：

TORNIEPORTHOETTING, IC

KLAPOTKE, TM

机构：

[1] Institut Für Anorganische Und Analytische Chemie, Technische Universität Berlin, Berlin

来源：

HETEROATOM CHEMISTRY | 1993年 / 4卷 / 06期

关键词：

D O I：

10.1002/hc.520040605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review is not exhaustive in scope but rather focuses on the most recent years of work in the field of cationic halogens, covering the literature up to mid 1992. This area is still currently developing. The review summarizes structure, preparation, and reactivity of cationic halogens. Modern theoretical aspects (ab initio MO calculations) as well as the energetics (thermodynamics) of these species are also included. In particular, the symmetric and unsymmetric structures of heteropolyatomic cations, the charge delocalization and bond lengths alternation in nppi-nppi species (n < 2), and the dimerization by pi-pi interactions are discussed.

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页码：543 / 552

页数：10

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