TRIS-(TRIMETHYLSILYL)SILANE IN THE DEOXYGENATION OF LONG-CHAIN UNSATURATED ALCOHOLS CONVERTS CIS TO TRANS ISOMERS

被引：4

作者：

JOHNSON, DW

POULOS, A

机构：

[1] Department of Chemical Pathology, Adelaide Children's Hospital, North Adelaide, SA 5006

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 15期

关键词：

D O I：

10.1016/0040-4039(92)88137-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

During radical deoxygenation reactions tris (trimethylsilyl)silane can cause cis to trans isomerization and reduction of remote double bonds in contrast to tributyltin hydride.

引用

页码：2045 / 2048

页数：4

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