SYNTHESIS AND STRUCTURE OF SULFIDE ALUMINATE SODALITES

被引：25

作者：

BRENCHLEY, ME ^{[1
]}

WELLER, MT ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 10期

关键词：

SODALITE; ALUMINATE; SULFIDE; X-RAY DIFFRACTION;

D O I：

10.1039/jm9920201003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The compounds Sr8[Al12O24]S2 and Ca8[Al12O24]S2 have been prepared by reduction of the corresponding sulfate materials, M64[Al96O192].(SO4)16 via an intra-cage reaction. The materials crystallise with the simple body-centred cubic sodalite structure. Profile refinement of powder X-ray data has been undertaken showing a tetrahedral coordination around sulfur and a distorted sevenfold coordination for the alkaline-earth metals.

引用

页码：1003 / 1005

页数：3

共 20 条

[1] CHEMISTRY OF SOIL MINERALS .6. SALT ENTRAINMENT BY SODALITE AND CANCRINITE DURING THEIR SYNTHESIS [J].

BARRER, RM ;

COLE, JF .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (09) :1516-&

[2] SYNTHESIS OF PHOTOCHROMIC AND CATHODOCHROMIC SODALITE [J].

CHANG, IF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1974, 121 (06) :815-820

[3] STRUCTURE OF CUBIC ALUMINATE SODALITE, SR8[AL12O24](CRO4)2 [J].

DEPMEIER, W ;

SCHMID, H ;

SETTER, N ;

WERK, ML .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :2251-2255

[4] STRUCTURE OF CUBIC ALUMINATE SODALITE CA8[AL12O24](WO4)2 IN COMPARISON WITH ITS ORTHORHOMBIC PHASE AND WITH CUBIC SR8[AL12O24](CRO4)2 [J].

DEPMEIER, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1988, 44 :201-207

[5] TETRAGONAL TETRAHEDRA DISTORTIONS IN CUBIC SODALITE FRAMEWORKS [J].

DEPMEIER, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (JUN) :185-191

[6] STRUPLO84, A FORTRAN PLOT PROGRAM FOR CRYSTAL-STRUCTURE ILLUSTRATIONS IN POLYHEDRAL REPRESENTATION [J].

FISCHER, RX .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1985, 18 (AUG) :258-262

[7] THE SYNTHESIS AND STRUCTURE OF SOME NEW SODALITES - THE LITHIUM HALOBERYLLOPHOSPHATES AND HALOBERYLLOARSENATES [J].

GIER, TE ;

HARRISON, WTA ;

STUCKY, GD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (09) :1169-1171

[8] THE CRYSTAL-STRUCTURES OF SODALITE-GROUP MINERALS [J].

HASSAN, I ;

GRUNDY, HD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (FEB) :6-13

[9]

HASSAN I, 1985, AM MINERAL, V70, P186

[10] INFRARED-SPECTRA OF ALUMINOGERMANATE-SODALITE AND ALUMINATE-SODALITE AND A RE-EXAMINATION OF THE RELATIONSHIP BETWEEN T-O BOND LENGTH, T-O-T ANGLE AND THE POSITION OF THE MAIN IR ABSORPTION-BAND FOR COMPOUNDS WITH FRAMEWORK STRUCTURES [J].

HENDERSON, CMB ;

TAYLOR, D .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1979, 35 (08) :929-935

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