SOME BY-PRODUCTS IN THE S(E)2' REACTIONS OF AN ALLENYLSILANE WITH ALDEHYDES

被引：18

作者：

ARCHIBALD, SC ^{[1
]}

FLEMING, I ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)77621-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction between the allenylsilane 1 and isobutyraldehyde 2 gives a minor byproduct 7, and the reaction between the allenylsilane 1 and the aldehyde 14 gives a succession of products 16, 18, and 19 arising from the phenyl group attacking the aldehyde intramolecularly faster than the allenylsilane can attack it.

引用

页码：2387 / 2390

页数：4

共 11 条

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