OXYGENATION UNDER UV-LIGHT OF ALLYLSILANES CATALYZED BY PALLADIUM(II) AND OF (ETA(3)-ALLYL)PALLADIUM COMPLEXES - A MECHANISTIC APPROACH

被引：12

作者：

MUZART, J

RIAHI, A

机构：

[1] Units de Recherche “Réarrangements Thermiques, Photochimiques”, CNRS, UFR Sciences, Université de Champagne-Ardenne

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1021/om00046a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of 1-phenyl-3-(trimethylsilyl)-1-propene, 1-phenyl-1-(trimethylsilyl)-2-propene, and bi(mu-chloro)bis(1,2,3-eta3)-1-phenylpropenyl)dipalladium as substrates led us to reject a free-radical mechanism for the title reactions and to retain an incorporation of oxygen at the level of a common organopalladium intermediate.

引用

页码：3478 / 3481

页数：4

共 41 条

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