RUTHENIUM CATALYZED REGIOSELECTIVE SYNTHESIS OF O-1-(1,3-DIENYL) CARBAMATES DIRECTLY FROM CO2

被引：42

作者：

HOFER, J ^{[1
]}

DOUCET, H ^{[1
]}

BRUNEAU, C ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,CHIM COORDINAT ORGAN LAB,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 50期

关键词：

RUTHENIUM CATALYSIS; ALKYNE ACTIVATION; DIENYL CARBAMATES;

D O I：

10.1016/0040-4039(91)80119-Q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

O-1-(1,3-dienyl) carbamates are obtained by regioselective addition of CO2 and secondary amines to isopropenylacetylene in the presence of a (Ph2P(CH2)(n)PPh2)Ru(eta-3-CH2-C(Me) = CH2)2 catalyst precursor.

引用

页码：7409 / 7410

页数：2

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