O-1-(1,3-BUTADIENYL) CARBAMATES AS DIELS-ALDER DIENES - STEREOSPECIFIC SYNTHESIS OF (+/-)-HERNANDULCIN AND CONGENERS

被引：13

作者：

DECUSATI, PF ^{[1
]}

OLOFSON, RA ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)88818-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The TiCl4-catalyzed addition of the title reactants to vinyl ketones regio- and stereospecifically yields cis-disubs, cyclohexenes which add RMgX stereospecifically to the ketone. A final product in this sequence is the intensely sweet sesquiterpene, hernandulcin. © 1990.

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页码：1409 / 1412

页数：4

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