NONVERTICAL TRIPLET ENERGY-TRANSFER TO A SEVERELY NONPLANAR 1,3-DIENE - PROPOSAL OF A MECHANISM-BASED ON PROGRESSIVE ENDOTHERMICITY OF VERTICAL TRANSFER TO INDIVIDUAL SINGLE-BOND TORSIONAL LEVELS

被引：12

作者：

GORMAN, AA ^{[1
]}

HAMBLETT, I ^{[1
]}

RUSHTON, FAP ^{[1
]}

UNETT, DJ ^{[1
]}

机构：

[1] CHRISTIE HOSP & HOLT RADIUM INST,PATERSON INST CANC RES,MANCHESTER M20 9BX,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 12期

关键词：

D O I：

10.1039/c39930000983

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1,3-diene unit in trans-beta-ionol exhibits extreme 'nonvertical' behaviour in accepting triplet energy from a series of donors, a result strongly supporting a mechanism herein presented, which depends on the modes of single-bond torsion available to non-planar molecules and the relative dispositions of their S0 and T1 surfaces with respect to such torsion.

引用

页码：983 / 984

页数：2

共 12 条

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