STUDY OF XANES AS USED FOR DETERMINING THE NEAR-NEIGHBOR DISTANCES IN SOME COBALT SYSTEMS

被引：1

作者：

CHAKRABORTY, AK ^{[1
]}

CHETAL, AR ^{[1
]}

SARODE, PR ^{[1
]}

机构：

[1] UNIV GOA,DEPT PHYS,GOA,INDIA

来源：

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH | 1992年 / 130卷 / 01期

关键词：

D O I：

10.1002/pssa.2211300103

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

X-ray cobalt K-absorption edges in the cobalt systems CoO, CoAl2O4, CoMoO4, Co(NO3)2 . 6 H2O, Co(C2H3O2)2 . 4 H2O, bieberite (CoSO4 mineral form), CoSO4 - 7 H2O, Co(CHO2)2 . 2 H2O are studied using a Cauchois-type X-ray spectrograph. The three XANES structures A, B, and C are observed in the spectra of these systems. The formula, proposed by Mahto and Chetal, is applied to XANES structures A and C to determine the near-neighbour distance in the above systems. The results obtained agree fairly well with the crystallographic values.

引用

页码：19 / 23

页数：5

共 26 条

[1] ABINITIO STUDIES OF X-RAY ABSORPTION-EDGE IN COPPER-COMPLEXES .1. ATOMIC CU2+ AND CU(II)CL2 [J].