NA+ COORDINATION IN SODIUM DIBORATE AND TRIBORATE GLASSES BY X-RAY-DIFFRACTION

被引：23

作者：

MEDDA, MP ^{[1
]}

MUSINU, A ^{[1
]}

PICCALUGA, G ^{[1
]}

PINNA, G ^{[1
]}

机构：

[1] UNIV CAGLIARI,DIPARTIMENTO SCI CHIM,VIA OSPED 72,I-09124 CAGLIARI,ITALY

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1993年 / 162卷 / 1-2期

关键词：

D O I：

10.1016/0022-3093(93)90748-M

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Na+ coordination in diborate (Na2O-2B2O3) and triborate (Na2O-3B2O3) glasses was investigated by X-ray diffraction through a difference method in which radial distribution functions of lithium borate samples are subtracted from those of sodium borate glasses of the same molar composition. The difference curves exhibited peaks arising from the distribution of nearest neighbour O atoms around Na+ ions. The quantitative analysis of these peaks and a careful evaluation of the reliability of structural parameters were performed. Average coordination numbers were 4.0+/-0.4 for diborate and 4.8+/-0.5 for triborate. Finally, a comparison was made of Na+ environments in glasses and crystals of equal composition, and the similarities and the differences were discussed.

引用

页码：128 / 135

页数：8

共 34 条

[1] X-ray diffraction study of soda-boric oxide glass [J].

Biscoe, J ;

Warren, BE .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1938, 21 (08) :287-293

[2] X-ray study of boric oxide-silica glass [J].

Biscoe, J ;

Robinson, CS ;

Warren, BE .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1939, 22 :180-184

[3]

Bray P. J., 1988, Magnetic Resonance Review, V13, P263

[4]

CHRYSSIKOS GD, 1990, PHYS CHEM GLASSES, V31, P109

[5] X-RAY-DIFFRACTION INVESTIGATION OF CO(II) IONS IN BOROSILICATE GLASSES [J].

CORRIAS, A ;

MAGINI, M ;

DEMORAES, M ;

SEDDA, AF ;

MUSINU, A ;

PASCHINA, G ;

PICCALUGA, G .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (10) :5769-5774

[6]

CORRIAS A, 1992, TRENDS CHEM PHYS, V2, P79

[7] THE STRUCTURE OF DENSE-PACKED METALLIC AND OXIDE GLASSES [J].

ECKERSLEY, MC ;

GASKELL, PH .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 95-6 :31-44

[8] STRUCTURAL ORDERING IN A CALCIUM SILICATE GLASS [J].

ECKERSLEY, MC ;

GASKELL, PH ;

BARNES, AC ;

CHIEUX, P .

NATURE, 1988, 335 (6190) :525-527

[9] STRUCTURE AND CHEMICAL DURABILITY OF ZINC-CONTAINING GLASSES [J].

ENNAS, G ;

MUSINU, A ;

PICCALUGA, G ;

MONTENERO, A ;

GNAPPI, G .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 125 (1-2) :181-185

[10]

ENNAS G, 1993, Z NATURFORSCH A, V48, P599

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