THE NATURE OF THE TRANSITORY PRODUCT IN THE GAS-PHASE OZONOLYSIS OF ETHENE

被引：78

作者：

NEEB, P

HORIE, O

MOORTGAT, GK

机构：

[1] Max-Planck-Institut für Chemie, Division of Atmospheric Chemistry, D-55020 Mainz

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 246卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(95)01073-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

One of the reactants for the formation of previously identified transitory product in the gas-phase ozonolysis of C2H4 was shown to be HCOOH. The most probable structure of this compound is HOO-CH2-O-CHO. Its concentration increased with the addition of HCOOH but decreased with the addition of HCHO which had previously been assumed as one of the reactants. This compound slowly decomposed to formic acid anhydride and water.

引用

收藏

页码：150 / 156

页数：7

相关论文

共 22 条

[1] FORMATION OF OH RADICALS IN THE GAS-PHASE REACTIONS OF O3 WITH A SERIES OF TERPENES [J].

ATKINSON, R ;

ASCHMANN, SM ;

AREY, J ;

SHOREES, B .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D5) :6065-6073

[2]

Bailey P. S., 1978, OZONATION ORGANIC CH, V1

[3] STUDIES ON THE FORMATION OF H2O2 IN THE OZONOLYSIS OF ALKENES [J].

BECKER, KH ;

BECHARA, J ;

BROCKMANN, KJ .

ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1993, 27 (01) :57-61

[4]

Benson, 1976, THERMOCHEMICAL KINET, V23, P613

[5] MECHANISM OF OZONOLYSIS [J].

CRIEGEE, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (11) :745-752

[6]

Criegee R, 1975, ANGEW CHEM-GER EDIT, V87, P765, DOI [10.1002/ange.19750872104, DOI 10.1002/ANGE.19750872104]

[7] A METHOD OF CALIBRATION OF THE FORMIC-ACID MONOMER CONCENTRATION IN THE GAS-PHASE [J].

FINKBEINER, M ;

NEEB, P ;

HORIE, O ;

MOORTGAT, GK .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1995, 351 (06) :521-525

[8] HYDROXYMETHYL HYDROPEROXIDE AND BIS(HYDROXYMETHYL) PEROXIDE FROM GAS-PHASE OZONOLYSIS OF NATURALLY-OCCURRING ALKENES [J].

GAB, S ;

HELLPOINTNER, E ;

TURNER, WV ;

KORTE, F .

NATURE, 1985, 316 (6028) :535-536

[9] MECHANISM FOR THE REACTION OF CH2OO WITH SO2 [J].

HATAKEYAMA, S ;

KOBAYASHI, H ;

LIN, ZY ;

TAKAGI, H ;

AKIMOTO, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (17) :4131-4135

[10] REACTIONS OF CRIEGEE INTERMEDIATES IN THE GAS-PHASE [J].

HATAKEYAMA, S ;

AKIMOTO, H .

RESEARCH ON CHEMICAL INTERMEDIATES, 1994, 20 (3-5) :503-524