MOLECULAR ORDERING IN LANGMUIR-BLODGETT-FILMS OF TRIPLE CHAINED AMMONIUM AMPHIPHILES CONTAINING MESOGENIC MOIETIES

被引：8

作者：

EVERAARS, MD ^{[1
]}

MARCELIS, ATM ^{[1
]}

SUDHOLTER, EJR ^{[1
]}

机构：

[1] WAGENINGEN UNIV AGR,ORGAN CHEM LAB,6703 HB WAGENINGEN,NETHERLANDS

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1995年 / 102卷

关键词：

AMPHIPHILES; LANGMUIR-BLODGETT FILMS; MESOGENIC MOIETIES; MOLECULAR ORDERING;

D O I：

10.1016/0927-7757(95)03251-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A number of triple chained ammonium amphiphiles have been synthesized with cyano- and nitrobiphenyl, and azobenzene mesogenic moieties at the termini of their hydrophobic chains. These compounds exhibit liquid crystalline behaviour and form stable monolayers at the water-air interface. The monolayers give Z-type transfer onto hydrophilic quartz. However, the transferred material reorganizes and the morphology of the film appears to depend on the thermotropic properties. For the cyanoazobenzene containing Langmuir-Blodgett multilayers, molecular reorganization is observed upon irradiation with UV light or upon heating to give well ordered, centrosymmetric, homeotropically aligned assemblies.

引用

页码：117 / 126

页数：10