NEUTRAL GOLD(I) FLUORIDE DOES INDEED EXIST

被引：58

作者：

SCHRODER, D

HRUSAK, J

TORNIEPORTHOETTING, IC

KLAPOTKE, TM

SCHWARZ, H

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,D-10623 BERLIN,GERMANY

[2] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,BERLIN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199402121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AuF+ and AuF‐ can be neutralized in the gas phase. Neutralization‐reionization mass spectrometry thus provides proof of the existence of neutral AuF, which was predicted by theory. The upper and lower limits for the bond dissociation energy could also be deduced: 68 kcal mol−1 < BDE < 85 kcal mol−1. The AuF ions are generated by electron impact ionization from AuF3. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：212 / 214

页数：3

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