SOLUBLE (PHTHALOCYANINATO)RUTHENIUM(II) PHOSPHANE COMPLEXES

被引：11

作者：

BULATOV, A ^{[1
]}

KNECHT, S ^{[1
]}

SUBRAMANIAN, LR ^{[1
]}

HANACK, M ^{[1
]}

机构：

[1] UNIV TUBINGEN, LEHRSTUHL ORGAN CHEM 2, INST ORGAN CHEM, MORGENSTELLE 18, D-72076 TUBINGEN, GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 11期

关键词：

PHTHALOCYANINATO COMPLEXES; RUTHENIUM COMPLEXES; PHOSPHANES;

D O I：

10.1002/cber.19931261136

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hitherto unknown ruthenium phthalocyanine complexes with phosphane ligands - PcRu(PEt2Ph)2 (1) and PcRu(PPh3)2 (2) - soluble in common organic solvents were prepared. Two methods were used for their synthesis: 1) Reaction of phthalonitrile with [Ru2Cl3(PEt2Ph)6]Cl in n-pentanol in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and 2) reaction of PcRu with the corresponding phosphanes. The products 1 and 2 were characterized by their IR, UV/Vis, FD-MS, and H-1-NMR data.

引用

页码：2565 / 2566

页数：2

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