TETRAZINE-BRIDGED PHTHALOCYANINATO METAL-COMPLEXES AS SEMICONDUCTING MATERIAL

被引：32

作者：

HANACK, M

LANGE, A

GROSSHANS, R

机构：

[1] Institut für Organische Chemie, D-7400 Tübingen

来源：

SYNTHETIC METALS | 1991年 / 45卷 / 01期

关键词：

D O I：

10.1016/0379-6779(91)91847-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis and semiconducting properties of two tetrazine-bridged phthalocyaninato-transition metal complexes [(me8)PcFe(tz)]n and [PcRu(me2tz)]n and the monomeric complexes PcML2 (M = Fe, L = me2tZ, M = Ru, L = me2pdz, me2tZ) are reported. Both tetrazine-bridged systems exhibit good semiconducting properties without oxidative doping. The reason for this behaviour in comparison to the corresponding pyrazine-bridged complexes, e.g. [PcM(pyz)]n (M = Fe, Ru), and the tetrazine-bridged system [(CN)4PcFe(tz)]n is discussed. In addition, the preparation of the bridged complex [PcFe(bpytz)]n is described.

引用

页码：59 / 70

页数：12

共 37 条

[1] THEORETICAL-STUDY OF THE ELECTRICAL BEHAVIOR OF ONE-DIMENSIONAL METALLOPHTHALOCYANINES AND RELATED METALLOMACROCYCLIC COMPOUNDS [J].