TRIETHYLBORANE INDUCED RADICAL REACTION OF KETENE SILYL ACETALS WITH POLYHALOMETHANES - SYNTHESIS OF 3,3-DIHALOACRYLATES AND 3-HALOACRYLATES

被引：13

作者：

SUGIMOTO, J

MIURA, K

OSHIMA, K

UTIMOTO, K

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 08期

关键词：

D O I：

10.1246/cl.1991.1319

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of ketene octyl t-butyldimethylsilyl acetal with tetrabromomethane or tribromomethane in the presence of a catalytic amount of triethylborane gave octyl 3,3-dibromoacrylate or octyl (E)-3-bromoacrylate, respectively.

引用

页码：1319 / 1322

页数：4

共 6 条

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[5] TRIETHYLBORANE INDUCED PERFLUOROALKYLATION OF SILYL ENOL ETHERS OR GERMYL ENOL ETHERS WITH PERFLUOROALKYL IODIDES
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[6] ACTIVATION OF POLYHALOALKANES BY PALLADIUM CATALYST - FACILE ADDITION OF POLYHALOALKANES TO OLEFINS
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