COPPER (II) AND PALLADIUM (II) COMPLEXES WITH 1,3-BIS-[3-(5-AMINO-1,2,4-TRIAZOLYL]TRIAZENE AND HALOGENO (PSEUDOHALOGENO) LIGANDS - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION

被引：7

作者：

HANOT, V

ROBERT, T

VANDERELST, L

机构：

[1] UNIV MONS,DEPT GEN CHEM,PL PARC 20,B-7000 MONS,BELGIUM

[2] UNIV MONS,NUCL MAGNET RESONANCE LAB,B-7000 MONS,BELGIUM

[3] UNIV MONS,DEPT ORGAN CHEM,B-7000 MONS,BELGIUM

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 07期

关键词：

D O I：

10.1080/00945719408001394

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title ligand (hereafter abbreviated as BATTH) is composed of a triazenic and two triazolic functional groups. The synthesis of metal complexes of general formula [M(BATT)X] (M=Cu(II), X=Cl, Br, I, SCN, CN; M=Pd(II), X=Cl, Br), and of the intermediate product [Cu(BATT)H2O]NO3 are reported. These complexes (including N-15 isotopes) are characterized by IR, micro-Raman, NMR (H-1, C-13) and UV-visible spectroscopies. From these results, it is proposed that BATT-adopts a terdentate-planar mode of coordination involving the two triazole cycles and the N2 atom of the triazenido group, which appears as a new type of coordination for this group.

引用

页码：1191 / 1211

页数：21

共 26 条

[11] CATENA-MU-(3,5-DIAMINO-1,2,4-TRIAZOLE N-1, N-3)-BIS(THIOCYANATO-N) CADMIUM(II) - SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE, AND INFRARED AND RAMAN CHARACTERIZATION [J].