CHARACTERIZATION OF THERMAL SPRAYED HYDROXYAPATITE POWDERS AND COATINGS

被引:32
作者
KHOR, KA
CHEANG, P
机构
[1] NANYANG TECHNOL UNIV, SCH MECH & PROD ENGN, SINGAPORE 2263, SINGAPORE
[2] NANYANG TECHNOL UNIV, SCH APPL SCI, SINGAPORE 2263, SINGAPORE
关键词
AGGLOMERATION; FEEDSTOCK; HYDROXYAPATITE; POWDER MORPHOLOGY; SPHEROIDIZATION; X-RAY DIFFRACTION;
D O I
10.1007/BF02648998
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Calcium phosphate materials such as hydroxvapatite (HA) have biocompatible properties that can promote osteogenesis or new bone formation. Thermal spraying is an economical and effective process for coating the hydroxyapatite onto metal. It has been reported that plasma spraying changes the degree of crystallinity as well as the phase composition of the HA. This article reports the preparation and characterization of HA powders and coatings by two thermal spray processes (plasma and combustion flame) and suggests that the state of the starting powder adversely affects the coating characteristics. The raw HA powders are synthesized through a chemical reaction involving calcium hydroxide and orthophosphoric acid. Phase analysis using an X-ray diffractometer revealed that the synthesized powder consists of predominantly the HA phase. Calcined and crushed HA powders of various size ranges were fed into the plasma jet to produce HA coatings on metallic substrates. In addition, some HA powders were sprayed into distilled water by plasma spraying and combustion flame spraying to study powder melting characteristics. Other samples were plasma sprayed onto a solid rotating target to study atomization and impact behavior. The morphology of the rapidly solidified powders and thermal sprayed coatings were examined by scanning electron microscopy (SEM). An X-ray sedimentation particle size analyzer, laser diffraction particle size analyzer, and image analyzer performed the particle size analysis. Preliminary results indicate that particle cohesion, size range, and thermal treatment in the plasma affect the phase and structure of the as-sprayed coating, and some post-spray treatment may be necessary to produce a dense and adherent coating with the desired biocompatible properties.
引用
收藏
页码:45 / 50
页数:6
相关论文
共 17 条
[1]  
Berndt C. C., 1990, Materials Forum, V14, P161
[2]   USE OF TRICALCIUM PHOSPHATE OR ELECTRICAL-STIMULATION TO ENHANCE THE BONE POROUS IMPLANT INTERFACE [J].
BERRY, JL ;
GEIGER, JM ;
MORAN, JM ;
SKRABA, JS ;
GREENWALD, AS .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1986, 20 (01) :65-77
[3]  
COOK SD, 1988, CLIN ORTHOP RELAT R, P225
[4]  
COOK SD, 1988, CLIN ORTHOP RELAT R, P303
[5]  
DENNISON HW, 1980, J BIOMED MATER RES, V14, P713
[6]  
DOUGLAS HH, 1990, THERMAL SPRAY RES AP, P419
[7]   EFFECT OF HYDROXYAPATITE IMPREGNATION ON SKELETAL BONDING OF POROUS COATED IMPLANTS [J].
DUCHEYNE, P ;
HENCH, LL ;
KAGAN, A ;
MARTENS, M ;
BURSENS, A ;
MULIER, JC .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1980, 14 (03) :225-237
[8]  
GROSS KA, 1990, THESIS MONASH U AUST
[9]  
JARCHO M, 1981, CLIN ORTHOP RELAT R, P259
[10]   HYDROXYLAPATITE SYNTHESIS AND CHARACTERIZATION IN DENSE POLYCRYSTALLINE FORM [J].
JARCHO, M ;
BOLEN, CH ;
THOMAS, MB ;
BOBICK, J ;
KAY, JF ;
DOREMUS, RH .
JOURNAL OF MATERIALS SCIENCE, 1976, 11 (11) :2027-2035