MOLECULAR-STRUCTURE AND ELECTRONIC-PROPERTIES OF OXOMOLYBDENUM(V) CATECHOLATE COMPLEXES

被引：20

作者：

BASU, P ^{[1
]}

BRUCK, MA ^{[1
]}

LI, Z ^{[1
]}

DHAWAN, IK ^{[1
]}

ENEMARK, JH ^{[1
]}

机构：

[1] UNIV ARIZONA, DEPT CHEM, TUCSON, AZ 85721 USA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

10.1021/ic00105a064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of mononuclear catecholato complexes of general formula LMoO(cat) (L = hydrotris(3,5-dimethyl-1-pyrazolyl)borate) have been prepared and characterized by cyclic voltammetry, IR, UV/vis, and EPR spectroscopy. The potential of the Mo(V/IV) redox couple is sensitive to the catechol substituents, but the nearly axial EPR parameters are primarily governed by the coordination environment about the metal and are similar for all of the compounds.

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页码：405 / 407

页数：3

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