IDENTIFICATION OF ISOPROPYLBIPHENYL, ALKYL DIPHENYLMETHANES, DIISOPROPYLNAPHTHALENE, LINEAR ALKYL BENZENES AND OTHER POLYCHLORINATED BIPHENYL REPLACEMENT COMPOUNDS IN EFFLUENTS, SEDIMENTS AND FISH IN THE FOX RIVER SYSTEM, WISCONSIN

Five polychlorinated biphenyl replacement dye solvents and a diluent present in carbonless copy paper were identified by gas chromatography/mass spectrometry in the following matrices: effluents from a de‐inking–recycling paper mill and a municipal wastewater treatment plant receiving wastewaters from a carbonless copy paper manufacturing plant; sediments; and fish collected near both discharges in the Fox River System, Wisconsin. An isopropylbiphenyl dye solvent mixture included mono‐, di‐ and triisopropylbiphenyls. Also identified were two dye solvent mixtures marketed under the trade name Santosol. Santosol 100 comprised ethyl‐diphenylmethanes (DPMs), benzyl‐ethyl‐DPMs, and dibenzyl‐ethyl‐DPMs. Similarly, Santosol 150 comprised dimethyl‐DPMs, benzyl‐dimethyl‐DPMs, and dibenzyl‐dimethyl‐DPMs. Diisopropylnaphthalenes, widely used as a dye solvent in Japan, were identified for the first time in the US environment. sec‐Butylbiphenyls and di‐sec‐butylbiphenyls, likely constituents of a sec‐butylbiphenyl dye solvent mixture, were tentatively identified. Linear alkyl benzenes (C10 to C13‐LABs) constituted the Alkylate 215 diluent mixture. Although known to occur as minor constituents in linear alkyl sulfonate detergents, LAB residues have not been previously attributed to commercial use of LABs. Copyright © 1990 John Wiley & Sons, Ltd.