REMOTE DIANIONS .5. SYNTHESIS OF DELTA-CONICEINE

被引：16

作者：

GREEN, DLC ^{[1
]}

THOMPSON, CM ^{[1
]}

机构：

[1] LOYOLA UNIV,DEPT CHEM,CHICAGO,IL 60626

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(00)93425-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A total synthesis of (+/-) delta-coniceine from 1,4-butanediol is herein reported. A pivotal transformation of the synthesis involves the addition of the dianion of 4-(phenylsulfonyl)butanoic acid to an activated imine followed by subsequent cyclization to form a substituted piperidone intermediate.

引用

页码：5051 / 5054

页数：4

共 22 条

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