IONIZATION AND DELOCALIZATION IN POTASSIUM ZEOLITE-L - A COMBINED NEUTRON-DIFFRACTION AND ELECTRON-SPIN-RESONANCE STUDY

被引：24

作者：

ANDERSON, PA

ARMSTRONG, AR

EDWARDS, PP

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

[2] RUTHERFORD APPLETON LAB,DIDCOT,OXON,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1002/anie.199406411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the reaction of dehydrated zeolite L with potassium vapor the guest metal atoms are spontaneously ionized and the resulting electrons delocalized among potassium cations that line the one‐dimensional channels of the zeolite host (see structure on the right). This phenomenon points out a possible approach to compounds containing ultrafine, conducting wires. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：641 / 643

页数：3

共 24 条

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