PLATINUM-COMPLEX-CATALYZED DEHYDROGENATIVE DOUBLE SILYLATION OF ACETYLENES, DIENES, AND OLEFINS WITH BIS(HYDROSILANE) COMPOUNDS

被引：98

作者：

TANAKA, M

UCHIMARU, Y

LAUTENSCHLAGER, HJ

机构：

[1] National Chemical Laboratory for Industry, Tsukuba

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1021/om00047a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Acetylenes, dienes, and olefins underwent dehydrogenative double silylation with bis(hydrosilane) species in the presence of platinum complex catalysts to give disilacyclic compounds in good yields.

引用

页码：16 / 18

页数：3

共 28 条

[1] RING-INSERTION AND RING-OPENING REACTIONS OF OCTAETHYLCYCLOTETRASILANE
CARLSON, CW
WEST, R
[J]. ORGANOMETALLICS, 1983, 2 (12) : 1801 - 1807
[2] Corey J. Y., 1988, SILICON CHEM
[3] SOME PLATINUM COMPLEXES CONTAINING CHELATING BIS(SILYL) LIGANDS
EABORN, C
METHAM, TN
PIDCOCK, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 63 (DEC16) : 107 - 117
[4] PLATINUM COMPLEX-CATALYZED DEHYDROGENATIVE MONOSILYLATION OF ALKENES WITH DISILANES
HAYASHI, T
KAWAMOTO, AM
KOBAYASHI, TA
TANAKA, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (07) : 563 - 564
[5] PLATINUM-COMPLEX-CATALYZED DOUBLE SILYLATION OF ETHYLENE AND NORBORNENE WITH DISILANES
HAYASHI, T
KOBAYASHI, T
KAWAMOTO, AM
YAMASHITA, H
TANAKA, M
[J]. ORGANOMETALLICS, 1990, 9 (01) : 280 - 281
[6] REACTIVITY OF CIS-BIS(DIMETHYLPHENYLSILYL)BIS(PHOSPHINE)PLATINUM COMPLEXES TOWARD UNSATURATED-COMPOUNDS RELEVANT TO DOUBLE SILYLATION
KOBAYASHI, T
HAYASHI, T
YAMASHITA, H
TANAKA, M
[J]. CHEMISTRY LETTERS, 1989, (03) : 467 - 470
[7] PALLADIUM CATALYZED DOUBLE SILYLATION OF BIS(TRIMETHYLSILYL)BUTADIYNE BY MEANS OF DISILANES
KUSUMOTO, T
HIYAMA, T
[J]. TETRAHEDRON LETTERS, 1987, 28 (16) : 1807 - 1810
[8] ADDITION OF CHLORODISILANES TO 1,3-BUTADIENES IN THE PRESENCE OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) - FACILE ROUTE TO (Z)-1,4-BIS(CHLOROSILYL)BUT-2-ENES
MATSUMOTO, H
SHONO, K
WADA, A
MATSUBARA, I
WATANABE, H
NAGAI, Y
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 199 (02) : 185 - 193
[9] ADDITION OF CHLORODISILANES TO ACETYLENE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(O) - A FACILE ROUTE TO (Z)-1,2-BIS(CHLOROSILYL)ETHENES
MATSUMOTO, H
MATSUBARA, I
KATO, T
SHONO, K
WATANABE, H
NAGAI, Y
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 199 (01) : 43 - 47
[10] (PPH3)3RHCL-CATALYZED HYDROSILYLATION OF UNSATURATED MOLECULES BY 1,2-BIS(DIMETHYLSILYL)ETHANE - UNPRECEDENTED RATE DIFFERENCE BETWEEN 2 SI-H BONDS
NAGASHIMA, H
TATEBE, K
ISHIBASHI, T
SAKAKIBARA, J
ITOH, K
[J]. ORGANOMETALLICS, 1989, 8 (10) : 2495 - 2496

← 1 2 3 →