NEW PORPHYCENE LIGANDS - OCTAETHYLPORPHYCENE AND ETIOPORPHYCENE (OEPC AND ETIOPC) TETRACOORDINATED AND PENTACOORDINATED ZINC-COMPLEXES OF OEPC

被引：129

作者：

VOGEL, E ^{[1
]}

KOCH, P ^{[1
]}

HOU, XL ^{[1
]}

LEX, J ^{[1
]}

LAUSMANN, M ^{[1
]}

KISTERS, M ^{[1
]}

AUKAULOO, MA ^{[1
]}

RICHARD, P ^{[1
]}

GUILARD, R ^{[1
]}

机构：

[1] UNIV BOURGOGNE,FAC SCI GABRIEL,SYNTH & ELECTROSYNTH ORGANOMET LAB,CNRS,UA 33,F-21100 DIJON,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Steric interactions of the substituents weaken the strong NH … N hydrogen bonds (typical for porphycenes) in 1 (R = Me, Et) by increasing the N … N distance. As a consequence the coordination of metal ions, in particular of Zn2+ ions, is facilitated. These findings can be expected to give impetus to the research into metalloporphycenes. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1600 / 1604

页数：5

共 37 条

[31]

VOGEL E, 1989, ISRAEL J CHEM, V29, P257

[32] NOVEL PORPHYRINOIDS [J].

VOGEL, E .

PURE AND APPLIED CHEMISTRY, 1990, 62 (03) :557-564

[33] 2,7,12,17-TETRAPROPYLPORPHYCENE - COUNTERPART OF OCTAETHYLPORPHYRIN IN THE PORPHYCENE SERIES [J].

VOGEL, E ;

BALCI, M ;

PRAMOD, K ;

KOCH, P ;

LEX, J ;

ERMER, O .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (09) :928-931

[34]

Vogel E., 1986, ANGEW CHEM, V98, P262

[35]

Vogel E, 1987, ANGEW CHEM, V99, P909

[36] ELECTRONIC STATES OF PORPHYCENES [J].

WALUK, J ;

MULLER, M ;

SWIDEREK, P ;

KOCHER, M ;

VOGEL, E ;

HOHLNEICHER, G ;

MICHL, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) :5511-5527

[37]

1989, CRC HDB CHEM PHYS, pF187

← 1 2 3 4 →