A SHORT SYNTHESIS OF SUBSTITUTED BETA-HYDROXY GAMMA-BUTYROLACTONES AND 2-DEOXYHEXOFURANOSIDES

被引：19

作者：

ESCUDIER, JM ^{[1
]}

BALTAS, M ^{[1
]}

GORRICHON, L ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,SYNTHESE & PHYSICOCHIM ORGAN LAB,CNRS,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 11期

关键词：

GAMMA-DELTA-EPOXY BETA-HYDROXYESTERS; LACTONIZATION; 2-DEOXYHEXOSES;

D O I：

10.1016/S0040-4039(00)91641-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The gamma,delta-epoxy beta-hydroxyestes obtained by diastereoselective aldolisation beetwen ester enolates and optically active alpha,beta-epoxyaldehydes, undergo quantitative stereocontrolled lactonisation which can be followed by reduction to provide 2-deoxy hexofuranosides.

引用

页码：1439 / 1442

页数：4

共 14 条

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