STRUCTURE AND MAGNETIC-PROPERTIES OF A NITROXIDE DIRUTHENIUM(II,III) COMPLEX, [RU-2(O(2)CCME(3))(4)(TEMPO)(2)] [RU-2(O(2)CCME(3))(4)(H2O)(2)](BF4)(2) (TEMPO=2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL)

被引：46

作者：

HANDA, M

SAYAMA, Y

MIKURIYA, M

NUKADA, R

HIROMITSU, I

KASUGA, K

机构：

[1] KWANSEI GAKUIN UNIV, SCH SCI, DEPT CHEM, NISHINOMIYA, HYOGO 662, JAPAN

[2] SHIMANE UNIV, FAC SCI, DEPT PHYS, MATSUE, SHIMANE 690, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 06期

关键词：

D O I：

10.1246/bcsj.68.1647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nitroxide complex, [RU(2)(O(2)CCMe(3))(4)(tempo)(2)][Ru-2(O(2)CCMe(3))(4)(H2O)(2)](BF4)(2) (tempo = 2,2,6,6-tetramethylpiperidine-1-oxyl) has been prepared and characterized by elemental analysis, X-ray crystal structure analysis, and variable temperature magnetic susceptibility and ESR spectrum measurements. A fairly large antiferromagnetic interaction (J=-130 cm(-1)) between the diruthenium core and the nitroxide radical has been observed.

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页码：1647 / 1653

页数：7

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