INTRAMOLECULAR ACTIVATION OF A C-F BOND AT PLATINUM(II) IN THE PRESENCE OF WEAKER C-X BONDS (X = H, CL AND BR)

被引:70
作者
CRESPO, M
MARTINEZ, M
SALES, J
机构
关键词
D O I
10.1039/c39920000822
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of [{PtMe2(mu-SMe2)}2] with the bifunctional imines (C6F5)CH=NCH2(2-XC6H4) (X = H, Cl and Br) leads to selective activation of the carbon-fluorine bond even in the presence of the weaker carbon-hydrogen, -chlorine and -bromine bonds.
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页码:822 / 823
页数:2
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