STRUCTURES OF STERICALLY OVERCROWDED AND CHARGE-PERTURBED MOLECULES .5. GAS-PHASE STRUCTURES OF FLATTENED AMINES .4. TRIISOPROPYLAMINE - A STERICALLY OVERCROWDED MOLECULE WITH A FLATTENED NC3 PYRAMID AND A P-TYPE NITROGEN ELECTRON PAIR

被引：91

作者：

BOCK, H ^{[1
]}

GOEBEL, I ^{[1
]}

HAVLAS, Z ^{[1
]}

LIEDLE, S ^{[1
]}

OBERHAMMER, H ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST PHYS & THEORET CHEM,W-7400 TUBINGEN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 02期

关键词：

D O I：

10.1002/anie.199101871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An extremely low first ionization energy, a reversible oxidizability, and an electron pair localized on the nitrogen atom in the radical cation characterizes triisopropylamine. The structure inferred from these properties, which is also supported by quantum mechanical calculations, is a flattened NX3 pyramid. Electron diffraction studies in the gas phase confirm the structure: the C-N-C angle is 119.2-degrees!

引用

页码：187 / 190

页数：4

共 31 条

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