RESCALED MEAN SPHERICAL APPROXIMATION FOR A COLLOIDAL SUSPENSION CONFINED IN A PLANAR SLIT

被引:12
作者
GONZALEZMOZUELOS, P
机构
[1] Departamento de Física, Centro de Investigación y de Estudios Avanzados, Instituto Politécnico National, 07000 México, D.F.
关键词
D O I
10.1063/1.464867
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper an extension of the rescaled mean spherical approximation is presented, which describes the local concentration profile of a colloidal suspension of charged particles confined between two parallel highly repulsive walls. The predictions of this scheme are in good quantitative agreement with those of the hypernetted-chain approximation. It is found that, for a given set of values of the bulk parameters, the structure of the concentration profile only depends on the value of the minimum of the external potential.
引用
收藏
页码:5747 / 5755
页数:9
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