RESCALED MEAN SPHERICAL APPROXIMATION FOR A COLLOIDAL SUSPENSION CONFINED IN A PLANAR SLIT

被引:12
作者
GONZALEZMOZUELOS, P
机构
[1] Departamento de Física, Centro de Investigación y de Estudios Avanzados, Instituto Politécnico National, 07000 México, D.F.
关键词
D O I
10.1063/1.464867
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper an extension of the rescaled mean spherical approximation is presented, which describes the local concentration profile of a colloidal suspension of charged particles confined between two parallel highly repulsive walls. The predictions of this scheme are in good quantitative agreement with those of the hypernetted-chain approximation. It is found that, for a given set of values of the bulk parameters, the structure of the concentration profile only depends on the value of the minimum of the external potential.
引用
收藏
页码:5747 / 5755
页数:9
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共 37 条
[21]  
Kress R, 1989, LINEAR INTEGRAL EQUA
[23]   LONG-TIME SELF-DIFFUSION IN CONCENTRATED COLLOIDAL DISPERSIONS [J].
MEDINANOYOLA, M .
PHYSICAL REVIEW LETTERS, 1988, 60 (26) :2705-2708
[24]   ON THE INTERACTION OF SPHERICAL DOUBLE-LAYERS [J].
MEDINANOYOLA, M ;
MCQUARRIE, DA .
JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (12) :6279-6283
[25]   STRUCTURAL-PROPERTIES OF SOLUTIONS OF SPHERICAL MICELLES - EFFECT OF FINITE SIZE OF SMALL IONS [J].
NAGELE, G ;
KLEIN, R ;
MEDINANOYOLA, M .
JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (05) :2560-2568
[26]  
Percus J. K., 1964, EQUILIBRIUM THEORY
[27]   DENSITY PROFILES AND PAIR CORRELATION-FUNCTIONS OF LENNARD-JONES FLUIDS NEAR A HARD-WALL [J].
PLISCHKE, M ;
HENDERSON, D .
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (05) :2846-2852
[28]   NEW, THERMODYNAMICALLY CONSISTENT, INTEGRAL-EQUATION FOR SIMPLE FLUIDS [J].
ROGERS, FJ ;
YOUNG, DA .
PHYSICAL REVIEW A, 1984, 30 (02) :999-1007
[29]   EFFECTS OF ION SIZES ON THE AGGREGATION AND SURFACE-CHARGE OF IONIC MICELLES IN 1-1 ELECTROLYTE-SOLUTIONS [J].
SHEU, EY ;
WU, CF ;
CHEN, SH .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (17) :4179-4187
[30]   STRUCTURE AND ORDERING IN DILUTE DISPERSIONS OF SPHERICAL-PARTICLES [J].
VANMEGEN, W ;
SNOOK, I .
JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (02) :813-817