SKELETAL REARRANGEMENT AND ACETYLIDE MIGRATION IN THE BUTTERFLY CLUSTER COMPLEXES WITH FORMULA CP-ASTERISK-WOS3(CO)(11)(C-CCH(2)OME)

被引：18

作者：

SU, PC

CHIANG, SJ

CHANG, LL

CHI, Y

PENG, SM

LEE, GH

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

[2] NATL TAIWAN UNIV,TAIPEI 10764,TAIWAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 10期

关键词：

D O I：

10.1021/om00010a054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Cp*W(CO)(3)(C=CCH(2)OMe) with Os-3(CO)(10)(NCMe)(2) in refluxing toluene afforded two cluster compounds (2a,b) with identical molecular formula CP*WOs3(CO)(11)-(C=CCH(2)OMe). Both compounds contain a butterfly skeletal arrangement and a multisite bound mu(4)-eta(2)-acetylide ligand. Complex 2a can be converted to 2b by relocating the Cp*W-(CO)(2) fragment from the hinge site to a wingtip position. The acetylide migration in 2b and the kinetic studies of the conversion between 2a and 2b are presented.

引用

页码：4844 / 4849

页数：6

共 54 条

[51] SYNTHESIS OF MIXED METAL-CLUSTERS FROM BINUCLEAR PRECURSORS - X-RAY STRUCTURE OF (ETA-5-C5H5)2NI2FE2(CO)5(MU-PPH2)(MU-4-ETA-2-C=CPH), A MOLECULE WITH A ETA-4-ACETYLIDE ON A SPIKED TRIANGULAR METAL FRAMEWORK [J].