GAS CHROMATOGRAPHIC-MASS SPECTROMETRIC STUDIESOF LONG CHAIN HYDROXY ACIDS .I. CONSTITUENT CUTIN ACIDS OF APPLE CUTICLE

被引：168

作者：

EGLINTON, G

HUNNEMAN, DH

机构：

[1] The Chemistry Department, The University of Glasgow, Glasgow, England

来源：

PHYTOCHEMISTRY | 1968年 / 7卷 / 02期

基金：

美国国家航空航天局;

关键词：

D O I：

10.1016/S0031-9422(00)86330-X

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The constituent cutin acids of apple cuticle have been determined by preparative TLC of the methyl esters followed by combined gas chromatography-mass spectrometry of the TMSi ethers of the methyl esters. This method may be applied to small amounts of cutin and has allowed the detection of a variety of hitherto unreported cutin acids. The principle cutina cids are 10,16-dihydroxyhexadecanoic acid, threo and erythro-9, 10,18-trihydroxyoctadecanoic, 16-hydroxyhexadecanoic, 18-hydroxyoctadec-9-enoic and 18-hydroxyoctadeca-9,12-dienoic. The location of the double bonds in the unsaturated compounds was determined by a novel method involving hydroxylation followed by GC-MS of the trimethylsilyl ethers of the resulting vic-dihydroxy compounds. © 1968.

引用

页码：313 / &

共 19 条

[11] MARTIN J. T., 1964, ANN REV PHYTO PATHOL, V2, P81, DOI 10.1146/annurev.py.02.090164.000501
[12] MARTIN JT, 1965, ANN REP LONG ASHTON, P251
[13] CHEMISTRY OF PLANT CUTICLES - STUDY OF CUTIN FROM AGAVE-AMERICANA L
MATIC, M
[J]. BIOCHEMICAL JOURNAL, 1956, 63 (01) : 168 - 178
[14] THE STRUCTURES OF 2 ACIDS FROM OLIVE LEAVES
MEAKINS, GD
SWINDELLS, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1959, (MAR): : 1044 - 1047
[15] RHODES E, 1925, P LEEDS PHIL SOC, V1, P27
[16] ROELOFSEN PA, 1951, PROTOPLASMA, V40, P11
[17] RYHAGE R, 1959, ARK KEMI, V13, P523
[18] RYHAGE R, 1964, ARK KEMI, V23, P167
[19] CHARACTERIZATION OF UNSATURATED HYDROCARBONS BY MASS SPECTROMETRY
WOLFF, RE
WOLFF, G
MCCLOSKE.JA
[J]. TETRAHEDRON, 1966, 22 (09) : 3093 - &

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