THE REACTION OF ALKYL DERIVATIVES OF YTTRIUM AND LUTETIUM WITH ORGANIC DISULFIDES AND DISELENIDES - THE MOLECULAR-STRUCTURE OF (((T)BUC5H4)2Y(MU-SEPH))2-CENTER-DOT-C6H6

被引：14

作者：

BELETSKAYA, IP

VOSKOBOYNIKOV, AZ

SHESTAKOVA, AK

YANOVSKY, AI

FUKIN, GK

ZACHAROV, LN

STRUCHKOV, YT

SCHUMANN, H

机构：

[1] MOSCOW CHEM & TECHNOL ORGANOELEMENT CPDS STATE SCI RES INST,111123 MOSCOW,RUSSIA

[2] AN NESMEYANOV ORGANOELEMENT CPDS INST,117813 MOSCOW,RUSSIA

[3] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,D-10623 BERLIN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 468卷 / 1-2期

关键词：

SULFUR; SELENIUM; YTTRIUM; LUTETIUM; BRIDGING LIGAND; CYCLOPENTADIENYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)80039-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimers {(tBuC5H4)2Ln(mu-Me)}2 (Ln=Y, or Lu) react with organic dichalcogenides R2E2 (E=S or Se; R=Ph, (n)Bu, (t)Bu or CH2Ph) to form {((t)BuC5H4)2Ln(mu-ER)}2 complexes with Ln-S or Ln-Se bonds. The molecular structure of {(tBuC5H4)2Ln(mu-SePh)}2 . C6H6 has been determined by X-ray diffraction (PBAR; a = 11.242(2) angstrom, b = 11.388(2) angstrom and c = 12.865(2) angstrom; alpha = 110.32(2)degrees; beta = 105.16(2)degrees; and gamma = 102.84(2)degrees; Z = 1; d(calc.) = 1.343 g cm-3; R = 0.0509 and R(omega) = 0.0532). The two yttrium atoms of the centrosymmetric dimeric molecule are bridged by two mu-SePh groups.

引用

页码：121 / 124

页数：4

共 16 条

[1] LANTHANIDE THIOLATE COMPLEXES - SYNTHESIS OF [EU(N(SIME3)2)(MU-SBUT)]2,[GD(N(SIME3)2)(MU-SBUT)]2,[Y(N(SIME3)2)(MU-SBUT)]2 AND THE X-RAY CRYSTAL-STRUCTURE OF THE GD COMPLEX [J].