VISCOELASTIC AND DIELECTRIC STUDY OF THERMALLY AGED ETHYLENE-PROPYLENE DIENE MONOMER (EPDM) COMPOUNDS

被引:36
作者
CHAILAN, JF
BOITEUX, G
CHAUCHARD, J
PINEL, B
SEYTRE, G
机构
[1] UNIV LYON 1,LEMPB,CNRS,URA 507,F-69622 VILLEURBANNE,FRANCE
[2] EDF,DER,DPT,CIMA 8,F-77250 MORET SUR LOING,FRANCE
关键词
D O I
10.1016/0141-3910(95)00005-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Three ethylene-propylene-hexadiene-1,4 terpolymer-based rubbers were submitted to thermal ageing in the temperature range 110-135 degrees C. Degradation effects on the rubbers were studied using a direct method, FTIR spectroscopy, and two indirect methods, dynamic mechanical analysis (DMA) and dielectrical analysis (DEA). The necessary sensitivity of such methods for the determination of the molecular effects of thermal ageing has been clearly illustrated. Changes in the main relaxation peak height allow the thermooxidation to be quantified.
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页码:397 / 403
页数:7
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