DEPROTONATION OF O-AMINOPHENOL AND O-AMINOTHIOPHENOL COMPLEXES OF NICKEL(2)AND PALLADIUM(2)

被引：18

作者：

WATT, GW

KNIFTON, JF

机构：

[1] Department of Chemistry, University of Texas at Austin, Austin

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 07期

关键词：

D O I：

10.1021/ic50065a037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the absence of air, o-aminophenol and o-aminothiophenol complexes of nickel(II) and palladium(II) are deprotonated by potassium amide in liquid ammonia and form potassium salts of the corresponding anions. These salts react with water to regenerate the parent complexes and with methyl iodide to form S-, O-, and N-methylated derivatives. © 1968, American Chemical Society. All rights reserved.

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页码：1443 / &

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