DEPROTONATION OF O-AMINOPHENOL AND O-AMINOTHIOPHENOL COMPLEXES OF NICKEL(2)AND PALLADIUM(2)

被引:18
作者
WATT, GW
KNIFTON, JF
机构
[1] Department of Chemistry, University of Texas at Austin, Austin
关键词
D O I
10.1021/ic50065a037
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the absence of air, o-aminophenol and o-aminothiophenol complexes of nickel(II) and palladium(II) are deprotonated by potassium amide in liquid ammonia and form potassium salts of the corresponding anions. These salts react with water to regenerate the parent complexes and with methyl iodide to form S-, O-, and N-methylated derivatives. © 1968, American Chemical Society. All rights reserved.
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页码:1443 / &
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[21]  
YAGUDAEV MR, 1963, IZV AKAD NAUK SSSR K, P2230