THE ORIGIN OF INFRARED-ABSORPTION BANDS OF SOOT IN THE REGION 750 TO 900 CM-1

被引：24

作者：

JASSIM, JA ^{[1
]}

LU, HP ^{[1
]}

CHUGHTAI, AR ^{[1
]}

SMITH, DM ^{[1
]}

机构：

[1] UNIV DENVER,DEPT CHEM,DENVER,CO 80208

来源：

APPLIED SPECTROSCOPY | 1986年 / 40卷 / 01期

关键词：

Spectroscopy; Absorption; -; Infrared;

D O I：

10.1366/0003702864815385

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

Bands which showed isotopic shifts upon regenerating soot functionalities with **1**8O//2 in the 1700 cm** minus **1 and 1200 cm** minus **1 regions were assigned to ketone-like carbonyl and ether-like groups on the surface, while the 1590 cm** minus **1 band, which fails to show any isotopic shift upon the reoxidation of soot with **1**8O//2 at high temperature, has been assigned to a carbonyl group conjugated with aromatic ring segments. Bands in the 800 cm** minus **1 were given no definite assignments. Logical origins of these bands could be the C-H out-of-plane bending of highly substituted aromatic compounds or stretching modes of peroxides or hydroperoxides. An attempt is made in this work to substantiate the origin of these bands.

引用

页码：113 / 116

页数：4