N,N-DISUBSTITUTED N'-FERROCENOYL THIOUREAS AS BIDENTATE LIGANDS FOR TRANSITION-METAL IONS - CRYSTAL-STRUCTURE OF BIS-(N,N-DIETHYL-N'-FERROCENOYLTHIOUREATO)NICKEL(II)

被引：24

作者：

SEIDELMANN, O ^{[1
]}

BEYER, L ^{[1
]}

RICHTER, R ^{[1
]}

机构：

[1] UNIV LEIPZIG,FAK CHEM & MINERAL,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 11期

关键词：

FERROCENE COMPLEXES; THIOUREA; HETERO METAL COMPLEXES; SYNTHESIS; CRYSTAL STRUCTURE;

D O I：

10.1515/znb-1995-1115

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N-diethyl-N'-ferrocenoyl-thiourea and N-(morpholino-thiocarbonyl)ferrocenecarboxylic amide have been prepared by the reaction of ferrocenoyl chloride with potassium thiocyanate and the respective amine in dry acetone. These bidentate ligands yield neutral heterometallic complexes with Ni(II), Cu(II), Mn(II) and Co(III). The dark brown air stable crystals of bis-(N,N-diethyl-N'-ferrocenoylthioureato)nickel(II) were characterized by X-ray structure determination. Lattice dimensions: a = 1870.9(1), b = 1161.5(1), c = 1491.4(1)pm; space group Pca2(1), Z = 4, R = 0.030 for 5707 observed reflections.

引用

页码：1679 / 1684

页数：6

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