IN7CL9 - A NEW OLD COMPOUND IN THE SYSTEM IN-CL

被引：8

作者：

BECK, HP

WILHELM, D

机构：

[1] Anorganische und Analytische Chemie und Radiochemie, Universität Saarbrücken, W-6600, Im Stadtwald

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 07期

关键词：

D O I：

10.1002/anie.199108241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neither In3Cl4 nor In4Cl5 accurately defines a phase whose existence was predicted by thermoanalytic methods. In fact a more apt formula is In7Cl9, for the phase which is prepared from InCl/InCl3 mixtures by sintering for 14 days at 220-250-degrees-C. The structure of the compound (part of which is shown on the right-In: small circles; Cl: large circles) reveals interesting crystallographic relationships to that of alpha-InCl and is important in the discussion on stereochemical activity of cations with ns2 configuration.

引用

页码：824 / 825

页数：2