SUBSTITUTION OF OH WITH NH2 IN CALIX[4]ARENES - AN APPROACH TO THE SYNTHESIS OF AMINOCALIXARENES

被引：42

作者：

OHSETO, F ^{[1
]}

MURAKAMI, H ^{[1
]}

ARAKI, K ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC ENGN,DEPT ORGAN SYNTH,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)91900-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

From p-t-butylcalix[4]arene bis(diethylphosphate) ester(1), monodehydroxymonoamino-p-t-butylcalix[4]arene(3) and diamino-p-t-butylcalix[4]arene(4) were synthesized in liquid ammonia-co-solvent in the presence of KNH2. This is the first successful example for the substitution of the OH group with the NH2 group.

引用

页码：1217 / 1220

页数：4

共 9 条

[1] FORMATION OF SOLVENT-SEPARATED ION-PAIRS IN CALIXARENE ESTER-ALKALI PICRATE COMPLEXES [J].

ARIMURA, T ;

KUBOTA, M ;

MATSUDA, T ;

MANABE, O ;

SHINKAI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) :1674-1676

[2] NEW METAL CATION-SELECTIVE IONOPHORES DERIVED FROM CALIXARENES - THEIR SYNTHESES AND ION-BINDING PROPERTIES [J].

CHANG, SK ;

CHO, I .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (02) :211-214

[3] MULTIPLE REDUCTIVE CLEAVAGE OF CALIXARENE DIETHYL PHOSPHATE-ESTERS - A ROUTE TO [1N]METACYCLOPHANES [J].

GOREN, Z ;

BIALI, SE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (05) :1484-1487

[4] REDUCTIVE AND OXIDATIVE REACTIONS OF CALIX[4]ARENE DERIVATIVES [J].

GRYNSZPAN, F ;

DINOOR, N ;

BIALI, SE .

TETRAHEDRON LETTERS, 1991, 32 (16) :1909-1912

[5] PARTIALLY OH DEPLETED CALIX[4]ARENES [J].

GRYNSZPAN, F ;

GOREN, Z ;

BIALI, SE .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) :532-536

[6]

Gutsche C. D., 1989, CALIXARENES

[7] SYNTHESIS, X-RAY CRYSTAL-STRUCTURES, AND CATION TRANSFER PROPERTIES OF ALKYL CALIXARYL ACETATES, A NEW SERIES OF MOLECULAR RECEPTORS [J].

MCKERVEY, MA ;

SEWARD, EM ;

FERGUSON, G ;

RUHL, B ;

HARRIS, SJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (07) :388-390

[8] SELECTIVELY DEHYDROXYLATED CALIX[4]ARENES AND 1,3-DITHIOCALIX[4]ARENES - NOVEL CLASSES OF CALIX[4]ARENES [J].

TING, YH ;

VERBOOM, W ;

GROENEN, LC ;

VANLOON, JD ;

REINHOUDT, DN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (20) :1432-1433

[9]

Ungaro R., 1984, J INCLUSION PHENOM, V2, P199, DOI DOI 10.1007/BF00663257

← 1 →