THE MECHANISM OF ENZYMATIC AND BIOMIMETIC OXIDATIONS OF AROMATIC SULFIDES AND SULFOXIDES

被引：35

作者：

BACIOCCHI, E ^{[1
]}

LANZALUNGA, O ^{[1
]}

MARCONI, F ^{[1
]}

机构：

[1] CNR,CTR STUDIO MECCANISMI REAZ,I-00185 ROME,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 52期

关键词：

D O I：

10.1016/0040-4039(94)88382-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C-H and/or C-S bond cleavage), which suggests the operation of an oxygen transfer mechanism.

引用

页码：9771 / 9774

页数：4

共 18 条

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