THE MECHANISM OF ENZYMATIC AND BIOMIMETIC OXIDATIONS OF AROMATIC SULFIDES AND SULFOXIDES

被引：35

作者：

BACIOCCHI, E ^{[1
]}

LANZALUNGA, O ^{[1
]}

MARCONI, F ^{[1
]}

机构：

[1] CNR,CTR STUDIO MECCANISMI REAZ,I-00185 ROME,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 52期

关键词：

D O I：

10.1016/0040-4039(94)88382-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C-H and/or C-S bond cleavage), which suggests the operation of an oxygen transfer mechanism.

引用

页码：9771 / 9774

页数：4

共 18 条

[11] Mariano P, 1993, ADV ELECT T, V3, P191
[12] MCMURRY TJ, 1992, CHEM REV, V92, P1411
[13] BIOMIMETIC OXIDATION OF ORGANIC SULFIDES WITH TPPFE(III)C1 IMIDAZOLE HYDROGEN-PEROXIDE
OAE, S
WATANABE, Y
FUJIMORI, K
[J]. TETRAHEDRON LETTERS, 1982, 23 (11) : 1189 - 1192
[14] PAUTET F, 1988, PHARMAZIE, P437
[15] ONE ELECTRON-TRANSFER MECHANISM IN THE ENZYMATIC OXYGENATION OF SULFOXIDE TO SULFONE PROMOTED BY A RECONSTITUTED SYSTEM WITH PURIFIED CYTOCHROME-P-450
WATANABE, Y
IYANAGI, T
OAE, S
[J]. TETRAHEDRON LETTERS, 1982, 23 (05) : 533 - 536
[16] MECHANISMS OF ENZYMATIC S-OXYGENATION OF THIOANISOLE DERIVATIVES AND O-DEMETHYLATION OF ANISOLE DERIVATIVES PROMOTED BY BOTH MICROSOMES AND A RECONSTITUTED SYSTEM WITH PURIFIED CYTOCHROME-P-450
WATANABE, Y
OAE, S
IYANAGI, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (01) : 188 - 195
[17] KINETIC-STUDY ON ENZYMATIC S-OXYGENATION PROMOTED BY A RECONSTITUTED SYSTEM WITH PURIFIED CYTOCHROME-P-450
WATANABE, Y
IYANAGI, T
OAE, S
[J]. TETRAHEDRON LETTERS, 1980, 21 (38) : 3685 - 3688
[18] ENZYMATIC OXIDATION OF ALKYL SULFIDES BY CYTOCHROME-P-450 AND HYDROXYL RADICAL
WATANABE, Y
NUMATA, T
IYANAGI, T
OAE, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (04) : 1163 - 1170

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