THERMODYNAMIC ORIGIN OF PROLYL PEPTIDE-BOND ISOMERS

被引：30

作者：

EBERHARDT, ES ^{[1
]}

LOH, SN ^{[1
]}

RAINES, RT ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT BIOCHEM,MADISON,WI 53706

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)93377-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preference for the trans isomer of prolyl peptide bonds arises almost entirely from enthalpy in aqueous buffer and in toluene.

引用

页码：3055 / 3056

页数：2

共 15 条

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[7] LOH SM, UNPUB
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[9] EVALUATION OF THERMODYNAMIC PARAMETERS FOR INTERCONVERSION OF CONFORMATIONAL ISOMERS OF 2 N-ACYL-PROLINES BY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY
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